The Dark History of a Potent Man-Made Poison
THE DARK HISTORY OF A POTENT MAN-MADE POISON
By Allan W. Maynard, MSc. and Wayne Dwernychuk, Phd
A group of chemicals classified as dioxins have a dark legacy that includes chemical warfare (Vietnam), an attempted high-profile assassination (Ukraine), the closure of the shellfish industry (Pacific Northwest). Co-author – Dr. Dwernychuk is a world-renowned expert on the impacts of dioxins in the environment.
WHAT IS DIOXIN?
Humans have discovered or created more than fifty million different chemicals here on earth. Over 90,000 chemicals are registered for use in the USA. The EU and Canada, having stricter policies, register about 25,000 chemicals for use. Of the thousands of man-made chemicals, only about 500 have been extensively studied for health and environmental impacts. We are living in a decades long public health experiment.
Dioxins are a group of chemically related compounds that contain carbon, oxygen, hydrogen, and chlorine, primarily created by unintentional human activity: industrial smelting, chlorine bleaching of paper pulp, herbicide/pesticide manufacturing, and burning waste.
The dioxin class of chemicals are considered “forever chemicals” because they break down very slowly. They cause severe health issues, including skin lesions, reproductive problems, developmental issues, and cancer. The World Health Organization (WHO) classifies the most toxic of this group 2,3,7,8 – tetrachlorodibenzo-para-dioxin (from now referred to as TCDD), as a known human carcinogen.
Over 80 million liters of defoliants (mostly Agent Orange) were sprayed during the Vietnam War
AGENT ORANGE – CHEMICAL WARFARE
ON AN EPIC SCALE
During the Vietnam War (mainly between 1962 – 1971), the United States military used Agent Orange as part of a large-scale defoliation program known as Operation Ranch Hand. Agent Orange is a mixture of herbicides that include 2,4-D (a commonly used weedkiller used in gardens) and 2,4,5-T. In the manufacturing of 2,4,5-T, the product became contaminated with dioxins – including the highly toxic TCDD. The contamination from the manufacturing process was unknown at the time.
Agent Orange (with its dioxin contamination) was sprayed over forests and farmlands to defoliate for military visibility, and to destroy crops believed to support opposing forces (the Viet Cong). It was applied at up to 20 times the recommend rate for killing plants. While it achieved some military objectives, the long-term consequences were devastating. Millions of Vietnamese civilians and U.S. veterans were exposed, leading to severe health problems including cancers, birth defects, and environmental destruction that persists today. Vietnam claims that the spraying caused over 400,000 deaths. The use of Agent Orange remains one of the most controversial aspects of the war, raising lasting ethical, legal, and humanitarian concerns.
Dr. W. Dwernychuk, then a senior associate with Hatfield Consultants, led a team of Canadian scientists to central Vietnam in the A Luoi Valley, the site of the infamous Hamburger Hill battle. The US established three special forces bases in the valley. Samples of environmental media and food stuffs were collected, with human blood and breast milk to determine the level of dioxin contamination in these materials. A huge volume of evidence was accumulated confirming the environmental and health consequences were a direct outcome of the chemical spraying.
Birth defects were common in areas sprayed with Agent Orange.
Dr. Dwernychuk also provided expert testimony in the US to support Vietnam War veterans. The 1991 Agent Orange Act allowed for over 650,000 vets to receive disability compensation for a host of illnesses (several cancers, Parkinson’s disease, type 2 diabetes, and coronary heart disease) associated with exposure to TCDD.
The ground-breaking work carried out by his firm is summarized in an historical account of the Vietnam War – “THE LONG RECKONING” by George Black and was also covered by CBS News “60 Minutes”. The link to the 60 minutes is given here and it is well worth the time to view. https://youtu.be/gFLdfR7O9xc?t=18 .
A short paper on the subject of ‘hot spots’ in Vietnam is given here: https://www.hatfieldgroup.com/wp-content/uploads/2020/05/chemosphere-hotspots.pdf
Victor Yushchenko – before and after being poisoned with TCDD
A POLITICAL ASSASSINATION ATTEMPT
In 2004 Ukraine was embroiled in a tense presidential election, the outcome of which was highly consequential. Victor Yushchenko, the pro-west and pro-EU candidate was running against the pro-Russia Prime Minister Viktor Yanukovych. In September of 2004, Yushchenko became ill with symptoms including a swollen pancreas severe abdominal pain and severe disfigurement from chloracne (see photo).
Austrian doctors and toxicology experts confirmed his face was affected by chloracne, caused by dioxin poisoning. Laboratory tests confirmed that the politician’s blood contained levels of TCDD 50,000 times above normal, the second highest concentration ever recorded. This deadly form of TCDD is manufactured in very small quantities and is only available as a laboratory reagent. It was obviously obtained in this form and likely administered with food.
Yushchenko claimed his opponents in government orchestrated the poisoning. Some reports, including insights from intelligence sources, suggested the orders for the attack came from Moscow. Despite the near-fatal poisoning, Yushchenko continued his campaign and won the presidency following a re-run of the election, which became known as the Orange Revolution (no relation to Agent Orange)
Kraft pulp and paper mill – Crofton BC
A LOCAL ISSUE – CONTAMINATION FROM PULP MILLS
Since the 1950s or so, British Columbia with its vast forest reserves, was home to a number of large pulp and paper mills. Most of these mills made “bleached kraft pulp” which is a high-quality, white pulp produced by cooking wood chips in an alkaline solution, then treating them with chemicals (like chlorine) to remove lignin and render the pulp white. This process increases brightness and softness, making it ideal for products requiring high purity, such as printing papers, tissues, and packaging, over the natural brown, unbleached alternative.
Another unknown at the time, the bleaching process produced dioxins (including TCDD) as a by-product and was discharged into the local waterways. Dr. Dwernychuk and I worked together on this project. Hatfield Consultants performed monitoring studies to follow the dioxin and other chemicals, in local sediments and animals many of which came to ASL (the laboratory I co-founded). The detection of dioxins and other contaminants resulted in the closure of all shellfish harvesting – from 1988 to the mid-90s.
Once the extent of the contamination from these pulp mills was determined, the Canadian government mandated all mills in Canada to switch from chlorine in the pulp bleaching process to chlorine dioxide, which did not result in dioxin contamination
The core maxim of the precautionary principle is, that an action (i.e. selling or use of a product) should not be taken when there is scientific uncertainty about its potential impact. In the case of Agent Orange particularly, that core principle was egregiously ignored. It is a sad and dark legacy with millions still paying the price.
More articles on toxic exposure and remedial/avoidance measures – https://www.environmentmatters.ca/our-toxic-world/



















